Tailoring Microporosity in Covalent Organic Frameworks

The microporosity of covalent organic frameworks (COFs) is tailored using a facile synthetic approach that introduces alkyl functionalities into the pore and generates networks with pore diameters between 1–2 nm. The added substituents significantly alter the host‐guest properties of the resulting m...

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Veröffentlicht in:Advanced materials (Weinheim) 2008-07, Vol.20 (14), p.2741-2746
Hauptverfasser: Tilford, R. William, Mugavero III, Sam J., Pellechia, Perry J., Lavigne, John J.
Format: Artikel
Sprache:eng
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Zusammenfassung:The microporosity of covalent organic frameworks (COFs) is tailored using a facile synthetic approach that introduces alkyl functionalities into the pore and generates networks with pore diameters between 1–2 nm. The added substituents significantly alter the host‐guest properties of the resulting materials.
ISSN:0935-9648
1521-4095
DOI:10.1002/adma.200800030