The isothermal section at 600 ∘C of the ternary Pr–Au–Sn phase diagram
The ternary Pr–Au–Sn isothermal section at 600 ∘C has been investigated by X-ray diffraction, optical and scanning electron microscopy and electron probe microanalysis. The ten new ternary phases τ 1 PrAu 2− x Sn x , τ 2 Pr 61Au 25Sn 14, τ 3 PrAu 6− x Sn x , τ 4 Pr 4Au 11Sn 5, τ 5 PrAu 2Sn, τ 6 Pr...
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| Veröffentlicht in: | Calphad 2009-03, Vol.33 (1), p.31-43 |
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| creator | Mazzone, D. Marazza, R. Riani, P. Zanicchi, G. Cacciamani, G. Fornasini, M.L. Manfrinetti, P. |
| description | The ternary Pr–Au–Sn isothermal section at 600
∘C has been investigated by X-ray diffraction, optical and scanning electron microscopy and electron probe microanalysis. The ten new ternary phases τ
1 PrAu
2−
x
Sn
x
, τ
2 Pr
61Au
25Sn
14, τ
3 PrAu
6−
x
Sn
x
, τ
4 Pr
4Au
11Sn
5, τ
5 PrAu
2Sn, τ
6 Pr
30Au
40+
x
Sn
30−
x
, τ
8 Pr
5AuSn
3, τ
9 Pr
3Au
6Sn
5, τ
10 Pr
2Au
3Sn
4, τ
11 Pr
2Au
3Sn
6 have been identified and the ternary equiatomic
τ
7
PrAuSn compound confirmed. The structures of some of these phases have been investigated by powder diffraction methods, and the results have been reported. The τ
3 PrAu
6−
x
Sn
x
solid solution at
x
=
1.77
and the τ
9 Pr
3Au
6Sn
5 ternary compound have been examined by single crystal method, resulting to be cubic
cI208-38.2, space group
Im
3
̄
, and orthorhombic
oP28, space group
Pmmn, respectively. The tie-triangles of the ternary section have been determined and their trend has been discussed. The results obtained have been compared to the Ce–Au–Sn ternary section at 750
∘C. |
| doi_str_mv | 10.1016/j.calphad.2008.09.017 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_33932110</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0364591608000989</els_id><sourcerecordid>33932110</sourcerecordid><originalsourceid>FETCH-LOGICAL-c255t-3262096b911b4c0b36318a19c7d5e600abb9b443b7181346e3613a60fb1bd3e83</originalsourceid><addsrcrecordid>eNqFkLtOwzAUhjOARCk8ApIntoTjOHHiCVUVN6kCJMps2c4JdZVLsVMkNkZ2FkaehUfpk-Cq3VnOWf6L_i-KzigkFCi_WCZGNauFqpIUoExAJECLg2gEjGdxLig_io69XwJAwVg2iu7nCyTW98MCXasa4tEMtu-IGggH-P0hm8_vKelrEgRkQNcp904e3ebja7IO56kjocwjqax6cao9iQ5r1Xg83f9x9Hx9NZ_exrOHm7vpZBabNM-HmKU8BcG1oFRnBjTjjJaKClNUOYZepbXQWcZ0QUvKMo6MU6Y41JrqimHJxtH5Lnfl-tc1-kG21htsGtVhv_aSMcFSSiEI853QuN57h7VcOduGEZKC3BKTS7knJrfEJAgZiAXf5c6HYcWbRSe9sdgZrKwLiGTV238S_gBT0Xps</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>33932110</pqid></control><display><type>article</type><title>The isothermal section at 600 ∘C of the ternary Pr–Au–Sn phase diagram</title><source>Elsevier ScienceDirect Journals</source><creator>Mazzone, D. ; Marazza, R. ; Riani, P. ; Zanicchi, G. ; Cacciamani, G. ; Fornasini, M.L. ; Manfrinetti, P.</creator><creatorcontrib>Mazzone, D. ; Marazza, R. ; Riani, P. ; Zanicchi, G. ; Cacciamani, G. ; Fornasini, M.L. ; Manfrinetti, P.</creatorcontrib><description>The ternary Pr–Au–Sn isothermal section at 600
∘C has been investigated by X-ray diffraction, optical and scanning electron microscopy and electron probe microanalysis. The ten new ternary phases τ
1 PrAu
2−
x
Sn
x
, τ
2 Pr
61Au
25Sn
14, τ
3 PrAu
6−
x
Sn
x
, τ
4 Pr
4Au
11Sn
5, τ
5 PrAu
2Sn, τ
6 Pr
30Au
40+
x
Sn
30−
x
, τ
8 Pr
5AuSn
3, τ
9 Pr
3Au
6Sn
5, τ
10 Pr
2Au
3Sn
4, τ
11 Pr
2Au
3Sn
6 have been identified and the ternary equiatomic
τ
7
PrAuSn compound confirmed. The structures of some of these phases have been investigated by powder diffraction methods, and the results have been reported. The τ
3 PrAu
6−
x
Sn
x
solid solution at
x
=
1.77
and the τ
9 Pr
3Au
6Sn
5 ternary compound have been examined by single crystal method, resulting to be cubic
cI208-38.2, space group
Im
3
̄
, and orthorhombic
oP28, space group
Pmmn, respectively. The tie-triangles of the ternary section have been determined and their trend has been discussed. The results obtained have been compared to the Ce–Au–Sn ternary section at 750
∘C.</description><identifier>ISSN: 0364-5916</identifier><identifier>DOI: 10.1016/j.calphad.2008.09.017</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><subject>Phase identification ; Rare-earth intermetallics ; Site occupancy ; Ternary alloy systems ; X-ray diffraction</subject><ispartof>Calphad, 2009-03, Vol.33 (1), p.31-43</ispartof><rights>2008 Elsevier Ltd</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c255t-3262096b911b4c0b36318a19c7d5e600abb9b443b7181346e3613a60fb1bd3e83</citedby><cites>FETCH-LOGICAL-c255t-3262096b911b4c0b36318a19c7d5e600abb9b443b7181346e3613a60fb1bd3e83</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0364591608000989$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Mazzone, D.</creatorcontrib><creatorcontrib>Marazza, R.</creatorcontrib><creatorcontrib>Riani, P.</creatorcontrib><creatorcontrib>Zanicchi, G.</creatorcontrib><creatorcontrib>Cacciamani, G.</creatorcontrib><creatorcontrib>Fornasini, M.L.</creatorcontrib><creatorcontrib>Manfrinetti, P.</creatorcontrib><title>The isothermal section at 600 ∘C of the ternary Pr–Au–Sn phase diagram</title><title>Calphad</title><description>The ternary Pr–Au–Sn isothermal section at 600
∘C has been investigated by X-ray diffraction, optical and scanning electron microscopy and electron probe microanalysis. The ten new ternary phases τ
1 PrAu
2−
x
Sn
x
, τ
2 Pr
61Au
25Sn
14, τ
3 PrAu
6−
x
Sn
x
, τ
4 Pr
4Au
11Sn
5, τ
5 PrAu
2Sn, τ
6 Pr
30Au
40+
x
Sn
30−
x
, τ
8 Pr
5AuSn
3, τ
9 Pr
3Au
6Sn
5, τ
10 Pr
2Au
3Sn
4, τ
11 Pr
2Au
3Sn
6 have been identified and the ternary equiatomic
τ
7
PrAuSn compound confirmed. The structures of some of these phases have been investigated by powder diffraction methods, and the results have been reported. The τ
3 PrAu
6−
x
Sn
x
solid solution at
x
=
1.77
and the τ
9 Pr
3Au
6Sn
5 ternary compound have been examined by single crystal method, resulting to be cubic
cI208-38.2, space group
Im
3
̄
, and orthorhombic
oP28, space group
Pmmn, respectively. The tie-triangles of the ternary section have been determined and their trend has been discussed. The results obtained have been compared to the Ce–Au–Sn ternary section at 750
∘C.</description><subject>Phase identification</subject><subject>Rare-earth intermetallics</subject><subject>Site occupancy</subject><subject>Ternary alloy systems</subject><subject>X-ray diffraction</subject><issn>0364-5916</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNqFkLtOwzAUhjOARCk8ApIntoTjOHHiCVUVN6kCJMps2c4JdZVLsVMkNkZ2FkaehUfpk-Cq3VnOWf6L_i-KzigkFCi_WCZGNauFqpIUoExAJECLg2gEjGdxLig_io69XwJAwVg2iu7nCyTW98MCXasa4tEMtu-IGggH-P0hm8_vKelrEgRkQNcp904e3ebja7IO56kjocwjqax6cao9iQ5r1Xg83f9x9Hx9NZ_exrOHm7vpZBabNM-HmKU8BcG1oFRnBjTjjJaKClNUOYZepbXQWcZ0QUvKMo6MU6Y41JrqimHJxtH5Lnfl-tc1-kG21htsGtVhv_aSMcFSSiEI853QuN57h7VcOduGEZKC3BKTS7knJrfEJAgZiAXf5c6HYcWbRSe9sdgZrKwLiGTV238S_gBT0Xps</recordid><startdate>200903</startdate><enddate>200903</enddate><creator>Mazzone, D.</creator><creator>Marazza, R.</creator><creator>Riani, P.</creator><creator>Zanicchi, G.</creator><creator>Cacciamani, G.</creator><creator>Fornasini, M.L.</creator><creator>Manfrinetti, P.</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SC</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>JQ2</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope></search><sort><creationdate>200903</creationdate><title>The isothermal section at 600 ∘C of the ternary Pr–Au–Sn phase diagram</title><author>Mazzone, D. ; Marazza, R. ; Riani, P. ; Zanicchi, G. ; Cacciamani, G. ; Fornasini, M.L. ; Manfrinetti, P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c255t-3262096b911b4c0b36318a19c7d5e600abb9b443b7181346e3613a60fb1bd3e83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Phase identification</topic><topic>Rare-earth intermetallics</topic><topic>Site occupancy</topic><topic>Ternary alloy systems</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mazzone, D.</creatorcontrib><creatorcontrib>Marazza, R.</creatorcontrib><creatorcontrib>Riani, P.</creatorcontrib><creatorcontrib>Zanicchi, G.</creatorcontrib><creatorcontrib>Cacciamani, G.</creatorcontrib><creatorcontrib>Fornasini, M.L.</creatorcontrib><creatorcontrib>Manfrinetti, P.</creatorcontrib><collection>CrossRef</collection><collection>Computer and Information Systems Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><jtitle>Calphad</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mazzone, D.</au><au>Marazza, R.</au><au>Riani, P.</au><au>Zanicchi, G.</au><au>Cacciamani, G.</au><au>Fornasini, M.L.</au><au>Manfrinetti, P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The isothermal section at 600 ∘C of the ternary Pr–Au–Sn phase diagram</atitle><jtitle>Calphad</jtitle><date>2009-03</date><risdate>2009</risdate><volume>33</volume><issue>1</issue><spage>31</spage><epage>43</epage><pages>31-43</pages><issn>0364-5916</issn><abstract>The ternary Pr–Au–Sn isothermal section at 600
∘C has been investigated by X-ray diffraction, optical and scanning electron microscopy and electron probe microanalysis. The ten new ternary phases τ
1 PrAu
2−
x
Sn
x
, τ
2 Pr
61Au
25Sn
14, τ
3 PrAu
6−
x
Sn
x
, τ
4 Pr
4Au
11Sn
5, τ
5 PrAu
2Sn, τ
6 Pr
30Au
40+
x
Sn
30−
x
, τ
8 Pr
5AuSn
3, τ
9 Pr
3Au
6Sn
5, τ
10 Pr
2Au
3Sn
4, τ
11 Pr
2Au
3Sn
6 have been identified and the ternary equiatomic
τ
7
PrAuSn compound confirmed. The structures of some of these phases have been investigated by powder diffraction methods, and the results have been reported. The τ
3 PrAu
6−
x
Sn
x
solid solution at
x
=
1.77
and the τ
9 Pr
3Au
6Sn
5 ternary compound have been examined by single crystal method, resulting to be cubic
cI208-38.2, space group
Im
3
̄
, and orthorhombic
oP28, space group
Pmmn, respectively. The tie-triangles of the ternary section have been determined and their trend has been discussed. The results obtained have been compared to the Ce–Au–Sn ternary section at 750
∘C.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.calphad.2008.09.017</doi><tpages>13</tpages></addata></record> |
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| ispartof | Calphad, 2009-03, Vol.33 (1), p.31-43 |
| issn | 0364-5916 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_33932110 |
| source | Elsevier ScienceDirect Journals |
| subjects | Phase identification Rare-earth intermetallics Site occupancy Ternary alloy systems X-ray diffraction |
| title | The isothermal section at 600 ∘C of the ternary Pr–Au–Sn phase diagram |
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