The Electron-Transfer Rate Processes In Biological Systems
The reaction coordinates for the electron transfer (ET) reactions are discussed. The channel-based reaction-diffusion equations are solved analytically for two biological electron transfer models, which allow us build an ET rate constant which modifies the Marcus-Jortner formula by adding a dynamic...
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| Hauptverfasser: | , , |
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| Format: | Tagungsbericht |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The reaction coordinates for the electron transfer (ET) reactions are discussed. The channel-based reaction-diffusion equations are solved analytically for two biological electron transfer models, which allow us build an ET rate constant which modifies the Marcus-Jortner formula by adding a dynamic correction factor. The dynamic correction factor can reduce the ET rate by orders of magnitude. The theory has been compared with experiment with fairly good result. |
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| ISSN: | 0094-243X |
| DOI: | 10.1063/1.3108381 |