Supramolecular Organization of ssDNA‐Templated π‐Conjugated Oligomers via Hydrogen Bonding

Supramolecular Organization of ssDNA‐Templated π‐Conjugated Oligomers via Hydrogen Bonding

The templated self‐assembly of water‐soluble π‐conjugated molecules bearing a diaminotriazine moiety H‐bonding to a single‐strand oligothymine template leads to defined structures. We study these assemblies with molecular modeling, circular dichroism spectroscopy, and scanning probe microscopy, to g...

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Veröffentlicht in:Advanced materials (Weinheim) 2009-03, Vol.21 (10‐11), p.1126-1130
Hauptverfasser: Surin, Mathieu, Janssen, Pim G. A., Lazzaroni, Roberto, Leclère, Philippe, Meijer, E. W., Schenning, Albertus P. H. J.
Format: Artikel
Sprache:eng
Schlagworte:
AFM
Conjugated oligomers
DNA
Molecular modeling
Templated self‐assembly
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Zusammenfassung:The templated self‐assembly of water‐soluble π‐conjugated molecules bearing a diaminotriazine moiety H‐bonding to a single‐strand oligothymine template leads to defined structures. We study these assemblies with molecular modeling, circular dichroism spectroscopy, and scanning probe microscopy, to get a better understanding of the factors governing the supramolecular organization and structural order.
ISSN:0935-9648
1521-4095
DOI:10.1002/adma.200801701