Total Synthesis of Marine Oxylipins Solandelactones A-H

The Solandelactones A–H have been synthesized via a short convergent approach utilizing common building blocks. Based on the diastereoselectivity of the crucial final addition step and on the comparison of prominent NMR data, a structural revision was necessary.

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Veröffentlicht in:Advanced synthesis & catalysis 2008-06, Vol.350 (9), p.1407-1412
Hauptverfasser: Pietruszka, Jörg, Rieche, Anja C. M.
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container_title Advanced synthesis & catalysis
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creator Pietruszka, Jörg
Rieche, Anja C. M.
description The Solandelactones A–H have been synthesized via a short convergent approach utilizing common building blocks. Based on the diastereoselectivity of the crucial final addition step and on the comparison of prominent NMR data, a structural revision was necessary.
doi_str_mv 10.1002/adsc.200800198
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source Wiley-Blackwell Journals
subjects asymmetric synthesis
cyclopropanes
natural products
structure elucidation
total synthesis
title Total Synthesis of Marine Oxylipins Solandelactones A-H
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