Influence of carbon content and microstructure on corrosion behaviour of low alloy steels in a Cl − containing environment

Corrosion behaviour of low alloy steels (A and B) with different carbon content was studied by a salt fog test and an outdoor test. A commercial weathering steel 09CuPCrNi was used for comparison. The corrosion resistance of steels A and B with homogeneous microstructures was better than that of the commercial weathering steel 09CuPCrNi in the salt fog test. Steel A with an ultra-low-carbon content had far less weathering resistance than the other steels in the outdoor test. Selective corrosion of large pearlite produces stress in initial corrosion product films. Uniform corrosion product films with few cracks tend to form on homogeneous microstructures such as ferrite and bainite, and this is advantageous for the formation of a compact rust layer in the initial stage of atmospheric corrosion. However, uniform microstructures will result in over even interfaces between rust layers and bases, which will lead to frequent peeling of rust layers from bases because stress is induced by large temperature fluctuations and wet-dry alternations. Protection of the rust layer on a low alloy steel is dependent on the rust density and the bonding performance of the rust-base rather than the proportion of the rust phase in the initial stage of atmospheric corrosion. These results indicate that homogenous microstructures, proper amounts of carbon content and fine carbon-rich phases that are produced by appropriate processes are beneficial for the corrosion resistance of steels.