In situ observation of composition profiles in the solution by X-ray penetration method

The X-ray penetration intensity during the diffusion process of NH 4Br into H 2O was measured by a CdTe line sensor as a function of time and it was converted to the NH 4Br composition using a calibration line. The diffusion coefficient of NH 4Br into H 2O was estimated to be 2.2×10 −5 cm 2/s by com...

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Veröffentlicht in:Journal of crystal growth 2008-04, Vol.310 (7), p.1487-1492
Hauptverfasser: Hayakawa, Yasuhiro, Hikida, Takuya, Morii, Hisashi, Konno, Akiko, Chen, Chung-Hao, Arafune, Kouji, Kawai, Hideki, Koyama, Tadanobu, Momose, Yoshimi, Ozawa, Tetsuo, Aoki, Toru
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container_end_page 1492
container_issue 7
container_start_page 1487
container_title Journal of crystal growth
container_volume 310
creator Hayakawa, Yasuhiro
Hikida, Takuya
Morii, Hisashi
Konno, Akiko
Chen, Chung-Hao
Arafune, Kouji
Kawai, Hideki
Koyama, Tadanobu
Momose, Yoshimi
Ozawa, Tetsuo
Aoki, Toru
description The X-ray penetration intensity during the diffusion process of NH 4Br into H 2O was measured by a CdTe line sensor as a function of time and it was converted to the NH 4Br composition using a calibration line. The diffusion coefficient of NH 4Br into H 2O was estimated to be 2.2×10 −5 cm 2/s by comparing the calculated results. The method was applied to the growth of InGaSb from the In–Ga–Sb solution. The indium composition profiles in the solution were measured and growth of InGaSb from the In–Ga–Sb solution was observed from the change of X-ray intensity. The growth region of InGaSb crystal was confirmed by the electron probe microanalysis. It was demonstrated that the X-ray penetration method was a powerful method to measure the composition profiles in the solution.
doi_str_mv 10.1016/j.jcrysgro.2007.12.010
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subjects A1. Mass transfer
A2. Growth from solutions
B1. Gallium compounds
B2. Semiconducting III–V materials
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Equations of state, phase equilibria, and phase transitions
Exact sciences and technology
Growth from solutions
Materials science
Methods of crystal growth
physics of crystal growth
Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation
Other interactions of matter with particles and radiation
Physics
Solubility, segregation, and mixing
phase separation
Theory and models of crystal growth
physics of crystal growth, crystal morphology and orientation
X-ray scattering
title In situ observation of composition profiles in the solution by X-ray penetration method
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