Quasielastic neutron scattering and diffusion in liquid lithium and lithium–hydrogen melt

Neutron quasielastic scattering experiments on liquid lithium (at 500 and 830 K) and a lithium-hydrogen melt (99 at.% Li7 and 1 at.% H at 830 K) have been performed. The characteristics of the diffusion mobility for lithium and hydrogen atoms have been extracted from the experimental results and ana...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of physics. Condensed matter 2008-03, Vol.20 (10), p.104201-104201 (4)
Hauptverfasser: Blagoveshchenskii, N M, Morozov, V A, Novikov, A G, Pashnev, M A, Savostin, V V, Shimkevich, A L, Sobolev, O V
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Neutron quasielastic scattering experiments on liquid lithium (at 500 and 830 K) and a lithium-hydrogen melt (99 at.% Li7 and 1 at.% H at 830 K) have been performed. The characteristics of the diffusion mobility for lithium and hydrogen atoms have been extracted from the experimental results and analyzed with the use of phenomenological and theoretical models. The self-diffusion coefficient in liquid lithium obtained for both temperatures is in agreement with values in the literature. The mechanism of hydrogen diffusion mobility in liquid lithium is discussed. It has been concluded that the hydrogen in the liquid lithium exists and diffuses in the form of the hydride LiH.
ISSN:0953-8984
1361-648X
DOI:10.1088/0953-8984/20/10/104201