Synthesis and properties of highly refractive polyimides derived from fluorene-bridged sulfur-containing dianhydrides and diamines
Highly refractive and transparent polyimides (PIs) based on fluorene-bridged and sulfur-containing monomers have been developed. An aromatic dianhydride, 4,4'-[p-thiobis(phenylenesulfanyl)]diphthalic anhydride (3SDEA), was polymerized with several fluorene-containing diamines, including commerc...
Gespeichert in:
Veröffentlicht in: | Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2008-02, Vol.46 (4), p.1510-1520 |
---|---|
Hauptverfasser: | , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | Highly refractive and transparent polyimides (PIs) based on fluorene-bridged and sulfur-containing monomers have been developed. An aromatic dianhydride, 4,4'-[p-thiobis(phenylenesulfanyl)]diphthalic anhydride (3SDEA), was polymerized with several fluorene-containing diamines, including commercially available 9,9'-bis(p-aminophenyl)fluorene (APF), 9,9'-bis[4-(p-aminophenoxy)phenyl]fluorene (OAPF), and newly synthesized 9,9'-bis[4-(p-aminophenyl)sulfanylphenyl]fluorene (ASPF) to afford series A PIs. Meanwhile, series B PIs were obtained from a new dianhydride, 4,4'-[(9H-fluorene-9-ylidene)bis(p-phenylsulfanyl)]diphthalic anhydride (FPSP) and two aromatic diamines, ASPF and 4,4'-thiobis[(p-phenylenesulfanyl)aniline] (3SDA) via a two-step polycondensation procedure. The PIs exhibit good thermal stabilities, such as relatively high glass transition temperatures in the range of 220-270 °C and high initial thermal decomposition temperatures (T₁₀%) exceeding 490 °C. The 9,9'-disubstituted fluorene moieties endow the PI films with good optical transparency. The optical transmittances of the PI films at 450 nm are all higher than 80% for the thickness of about 10 μm. Furthermore, the highly aromatic fluorene moiety and flexible thioether linkages in the molecular chains of the PIs provide them with high refractive indices of 1.6951-1.7258 and small birefringence of 0.0056-0.0070. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 1510-1520, 2008 |
---|---|
ISSN: | 0887-624X 1099-0518 |
DOI: | 10.1002/pola.22492 |