Effects of synthesis temperature on the microstructures and basic dyes adsorption of titanate nanotubes

The adsorption of two basic dyes (Basic Green 5 (BG5) and Basic Violet 10 (BV10)) onto titanate nanotubes (TNT) that were prepared via a hydrothermal method with different synthesis temperatures was studied to examine the potential of TNT for the removal of basic dyes from aqueous solution. Effects...

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Veröffentlicht in:Journal of hazardous materials 2008-02, Vol.150 (3), p.494-503
Hauptverfasser: Lee, Chung-Kung, Lin, Kuen-Song, Wu, Chian-Fu, Lyu, Meng-Du, Lo, Chao-Chun
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container_end_page 503
container_issue 3
container_start_page 494
container_title Journal of hazardous materials
container_volume 150
creator Lee, Chung-Kung
Lin, Kuen-Song
Wu, Chian-Fu
Lyu, Meng-Du
Lo, Chao-Chun
description The adsorption of two basic dyes (Basic Green 5 (BG5) and Basic Violet 10 (BV10)) onto titanate nanotubes (TNT) that were prepared via a hydrothermal method with different synthesis temperatures was studied to examine the potential of TNT for the removal of basic dyes from aqueous solution. Effects of synthesis temperature on the microstructures of TNT were characterized with transmission electron microscopy (TEM), X-ray diffraction (XRD), and nitrogen adsorption–desorption isotherms. For synthesis temperature greater than 160 °C, the microstructure of titanate might transform from nanotube into nanorod accompanying with the sharp decrease in the titanate interlayer spacing, BET surface area, and pore volume. Effects of the pore structure variation on the basic dyes adsorption of TNT were discussed. Moreover, the adsorption mechanisms of basic dyes from aqueous solution onto TNT were examined with the aid of model analyses of the adsorption equilibrium and kinetic data of BG5 and BV10. The regeneration of TNT was also briefly discussed.
doi_str_mv 10.1016/j.jhazmat.2007.04.129
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Effects of synthesis temperature on the microstructures of TNT were characterized with transmission electron microscopy (TEM), X-ray diffraction (XRD), and nitrogen adsorption–desorption isotherms. For synthesis temperature greater than 160 °C, the microstructure of titanate might transform from nanotube into nanorod accompanying with the sharp decrease in the titanate interlayer spacing, BET surface area, and pore volume. Effects of the pore structure variation on the basic dyes adsorption of TNT were discussed. Moreover, the adsorption mechanisms of basic dyes from aqueous solution onto TNT were examined with the aid of model analyses of the adsorption equilibrium and kinetic data of BG5 and BV10. 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subjects Adsorption
Applied sciences
Basic dyes
Chemical engineering
Coloring Agents - chemistry
Exact sciences and technology
Hot Temperature
Kinetics
Microscopy, Electron, Transmission
Nanorod
Nanotubes - chemistry
Nanotubes - ultrastructure
Pollution
Porosity
Surface Properties
Synthesis temperature
Titanate nanotubes
Titanium - chemistry
Water Pollutants, Chemical - chemistry
Water Purification - methods
X-Ray Diffraction
title Effects of synthesis temperature on the microstructures and basic dyes adsorption of titanate nanotubes
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