Effect of Zn/Si Ratio on the Microstructural and Microwave Dielectric Properties of Zn2SiO4 Ceramics
Zn2SiO4 ceramics synthesized by the conventional solid‐state method exhibited a low Q×f value, possibly due to the formation of a ZnO second phase. However, with a small ZnO reduction from the Zn2SiO4 ceramics, the ZnO second phase disappeared and grain growth occurred due to the formation of a Si‐r...
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Veröffentlicht in: | Journal of the American Ceramic Society 2007-10, Vol.90 (10), p.3127-3130 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Zn2SiO4 ceramics synthesized by the conventional solid‐state method exhibited a low Q×f value, possibly due to the formation of a ZnO second phase. However, with a small ZnO reduction from the Zn2SiO4 ceramics, the ZnO second phase disappeared and grain growth occurred due to the formation of a Si‐rich liquid phase. Specimens with a large grain size exhibited an improved Q×f value. In particular, the ceramics with nominal composition Zn1.8SiO3.8 sintered at 1300°C exhibited improved microwave dielectric properties of ɛr=6.6, Q×f=147 000 GHz, and τf=−22 ppm/°C. |
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ISSN: | 0002-7820 1551-2916 |
DOI: | 10.1111/j.1551-2916.2007.01891.x |