Evaluating long-term reductions in trace metal emissions from shipping in Shanghai

Shipping emissions are a major contributor to air pollution in coastal cities, and Shanghai Port, the busiest port in the world, handles over 40 million TEU annually. To mitigate shipping emissions, China introduced the Domestic Emission Control Area (DECA) policy in phases: DECA 1.0 in 2016 and DECA 2.0 in 2019. DECA 1.0 mandated low-sulfur fuels (0.5 %) at berth and near major ports, down from 1.5 %, and this requirement was extended to a 12-nautical-mile emission control zone in DECA 2.0. In this study, we conducted long-term online measurements of shipping emission tracer of vanadium (V) and nickel (Ni), at the Dian Shan Lake (DSL) supersite, located approximately 50 km from Shanghai waters. The observed V concentration exhibited a strong dependence on wind direction, with higher levels from spring to summer due to more frequent marine winds compared to other seasons. The long-term measurement showed a significant decrease in V concentrations, dropping from an annual mean of 7.08 ng m-³ during DECA 1.0 to 2.64 ng m-³ during DECA 2.0. The represents a year-on-year reduction of 63 % based on measurement. To remove the meteorological impact on the measured concentration, a Random Forest (RF) machine learning model and the Community Multiscale Air Quality (CMAQ 5.4) model were applied under a business-as-usual (BAU) scenario. Both models produced consistent results, showing a reduction of up to 82 % in V concentrations in April with more frequent marine winds, confirming regional air quality improvements post-DECA 2.0. Additionally, we found that Ni has other sources that require further control beyond shipping. The study highlights the importance of long-term measurements for understanding the impact of air quality policies on emission patterns. [Display omitted] •Elevated vanadium (V) concentrations in inland Shanghai are linked to marine winds.•V showed an annual reduction of 63 % in 2019 compared to 2016-2018.•Up to an 82 % reduction in V is attributed to the policy implemented in 2019.•Both machine learning and the air quality model show consistent quantitative reductions.•The reduction in nickel (Ni) is less pronounced, owing to other non-shipping emissions.