Occurrence and ecological risks of organophosphate esters in the sediments of Hangzhou Bay and the East China Sea

This study investigated 17 organophosphate esters (OPEs) in the surface sediments of Hangzhou Bay and the East China Sea. The mean concentration of ∑OPEs in Hangzhou Bay (235.3 ng/g) was slightly lower than that in the East China Sea (273.5 ng/g), with detected analytes dominated by Diethyl phosphate, Tris(2-chloropropyl) phosphate, and Tris(1-chloro-2-propyl) phosphate. Based on principal component analysis and cluster analysis for the source apportionment of OPEs, the results indicated that the high levels of OPEs in the East China Sea close to Yangtze River estuary can be attributed to a significant large-scale OPEs production site located along the southern Yellow Sea and the western coast of the East China Sea. Furthermore, the risk assessment conducted on aquatic organisms indicated the non-ecological risk of OPEs. However, future research should focus on the potential composite impacts of OPEs on the water systems and human health. •Seventeen OPEs were detected in marine sediment of Hangzhou Bay and the East China Sea.•The concentration levels of Σ17OPEs ranged from 50.49 to 653.06 ng/g.•ΣTCPP and Diethyl phosphate (mono&di) were the predominant compounds in sediment.•Most OPEs did not yield significant ecological risk, except for TBP.