Engineered biochar for in-situ and ex-situ remediation of contaminants from soil and water

Tailoring physical and chemical properties of biochar enhances its selectivity, treatability, and efficiency in contaminant remediation. Thus, engineered biochar has emerged as a promising remedy for both in-situ and ex-situ remediation of polluted soil and water. Several factors influence the effectiveness of engineered biochar, including feedstock sources, pyrolysis conditions, surface functionalization, mode of application, and site characteristics. The advantages and disadvantages of different modification approaches to engineered biochar and their specific treatability for in-situ and ex-situ remediation are obscure and must be adequately addressed. This review critically evaluates the application of engineered biochar for on/off-spot contamination management, taking into account the long-term stability and biocompatibility prospects. The properties of engineered biochar resulting from modification with clay minerals, nanoparticles, polymers, surfactants, and oxidants/reductants were critically reviewed. Recent progress and advances in remediation mechanisms and modes of application were elaborated for the effective removal of organic and inorganic contaminants, including heavy metals, pesticides, dyes, polycyclic aromatic hydrocarbons, per- and poly-fluoroalkyl substances, and agrochemicals. Several crucial parameters influence in-situ remediation, including the distribution of contaminants, background electrolytes, hydraulic conductivity, as well as dispersion and stability of adsorbents. Ex-situ remediation of pollutants relies heavily on adsorption or degradation kinetics, background electrolytes, adsorbent dose, and pollutant concentrations. In addition, factors restricting the application of engineered biochar were highlighted for long-term sustainable contaminant management and maintaining low environmental impact. Finally, the challenges and future perspectives of utilizing engineered biochar for field-scale demonstration of contaminated sites are proposed. [Display omitted] •Synthesis and application of engineered biochar (EB) were highlighted from field perspectives.•Tailored EB efficiently remediates organic and inorganic pollutants from soil and water.•Migration mechanisms of EB into sediment were underlined from in-situ context.•Desorption of contaminants from EB was appraised under biotic and abiotic factors.•Challenges and progress of EB were highlighted for field-scale demonstration.