A new portable open-path instrument for ambient NH3 and on-road emission measurements

•A portable open-path instrument based on DOAS was developed for mobile measurement of ambient NH3.•The on-road NH3 and NO concentrations were measured for the arterial highway of Shanghai.•The measured NH3/NO was associated to the proportions of light gasoline vehicles and heavy-duty diesel vehicles in the fleet.•The mileage-based NH3 emission factor was estimated to be 17.9 ± 6.3 mg/km per vehicle based on the tunnel measurement. Increased attentions to vehicle emission of NH3 have been paid since it is generally regarded as an important source in urban areas. Here, we developed a movable instrument based on Differential Optical Absorption Spectroscopy (DOAS) principle for detecting on-road NH3, which can avoid the losses in the sampling process attributed to the non-sampling methods. For this mobile DOAS, the temporal resolution, detection limit and relative error for NH3 were 1 min, 2.29 ppbv and 4.57% ± 2.44%, respectively. By employed to the on-road measurements along the arterial highway in Shanghai, the spatial distributions of NH3 and NO were obtained, and their dependence of traffic and road conditions were studied. The slopes of linear regression between NH3 and NO were 0.40, 0.02 and 0.07 on the Middle Ring Road, Outer Ring Road and Chongming Island Ring Road. It indicates that light gasoline vehicles (LGVs) were found to be the main contributor to NH3 emissions, while heavy-duty diesel vehicles (HDVs) mainly emitted NO. Based on the measured NH3 in the tunnel, the mileage-based NH3 emission factor per vehicle was estimated to be 17.9 ± 6.3 mg/km. The reported open-path instrument can be broadly used in on-road pollutant monitoring or vehicle emissions, and the measurements can reveal the real situation of emission characteristics, even find the abnormal operations of vehicle catalyst system. [Display omitted]