Electrochemical promoted C H bond chlorination of sulfoxonium ylides

Electrochemical promoted C H bond chlorination of sulfoxonium ylides

The first electrochemical promoted CH bond chlorination of sulfoxonium ylides was accomplished using magnesium chloride as the chlorine source, as well as a supporting electrolyte. This method does not require transition metal catalysts, external oxidants, and electrolytes, providing a green and mil...

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Veröffentlicht in:Tetrahedron letters 2023-01, Vol.114, p.154244, Article 154244
Hauptverfasser: Zhang, Li-Ming, Fu, Zi-Hao, Yuan, Da-Fu, Guo, Ming-Zhong, Li, Ming, Wen, Li-Rong, Zhang, Lin-Bao
Format: Artikel
Sprache:eng
Schlagworte:
chlorination
chlorine
electrochemistry
electrolytes
magnesium chloride
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Zusammenfassung:The first electrochemical promoted CH bond chlorination of sulfoxonium ylides was accomplished using magnesium chloride as the chlorine source, as well as a supporting electrolyte. This method does not require transition metal catalysts, external oxidants, and electrolytes, providing a green and mild route for the functionalization of sulfoxonium ylides.
ISSN:0040-4039
DOI:10.1016/j.tetlet.2022.154244