Recycling and reuse of waste agricultural plastics with hydrothermal pretreatment and low-temperature pyrolysis method

Recycling and reuse of agricultural plastics is an urgent worldwide issue. In this work, it is shown that low-density polyethylene (PE) typically used in mulch films can be converted into high-capacity P and N adsorbents through a two-step method that uses hydrothermal pretreatment (180 °C, 24 h) followed by pyrolysis at 500 °C with Ca(OH)2 additive. CaPE@HC500 materials prepared with the proposed two-step method were found to have high adsorption capacities for phosphate (263.6 mg/g) and nitrogen (200.7 mg/g) over wide ranges of pH (3–11). Dynamic adsorption of phosphate by CaPE@HC500 material in a packed-bed had a half-time breakthrough of 210 min indicating the feasibility of continuous systems. Material stability, cost, environmental-friendliness, and recyclability of the CaPE@HC500 material were determined to be superior to literature-proposed Ca-containing adsorbents. The two-step method for converting waste agricultural plastic mulch films into adsorbents is robust and highly-applicable to industrial settings. [Display omitted] •Mulch films-derived carbon via hydrothermal retreatment-pyrolysis and Ca(OH)2.•Mulch film pyrolysis temperature lowered to 500 °C; carbonization yield >68%.•High adsorption capacities (>263 mg/g) of P and N over pH values from 3 to 11.•Dynamic adsorption results show feasibility of adsorbent for continuous systems.•Life cycle ranking assessment to evaluate mulch film-derived product.