Investigating the potential of structurally defective UiO-66 for Sb (V) removal from tailing wastewater

Antimony contamination of tailings from the mining process remain attracted a great amount of concern. In this study, defective UiO-66-X crystal materials are rationally constructed using trifluoroacetic acid and hydrochloric acid as modulators for the removal of Sb(V) from actual tailing sand leachates. XRD and TG characterizations reveal that the number and kind of defects in UiO-66 are influenced by the type of modulators and the addition of trifluoroacetic acid makes UiO-66-TFA contain both cluster and ligand defects. Adsorption experiments show that UiO-66 and UiO-66-HCl achieve 100% removal of Sb(V) at pH 7.5 of the tailing sand leachate, and up to 90% removal of Sb(V) by the three materials at pH 2.5. It is noteworthy that the removal rate of Sb(V) by UiO-66-HCl is still satisfactory even under strongly acidic conditions at pH 0.5, with good potential for practical applications. Four kinetic models are used to fit the adsorption data and the analysis shows that the mechanism of Sb(V) adsorption by three adsorbent is all pseudo-second order and chemisorption acts as an important role in the adsorption process. In addition, the fixed bed adsorption experiments show that the material exhibit good prospects for practical applications. With the help of defect engineering strategy, UiO-66-Xs with structural defects were designed, and the differences in the removal performance of antimony in actual wastewater under different pH conditions were explored, providing new ideas for the removal of antimony in actual wastewater. [Display omitted] •The defective UiO-66 was designed with the help of defect engineering strategy.•The removal performance of Sb(V) by materials under different pH was explored.•The removal performance of Sb (V) varies among the three materials at different pH.•Fixed bed experiments showed that the material exhibited practical application value.