Green construction of biochar@NiFe2O4 nanocomposite for highly efficient photocatalytic remediation of pesticides from agriculture wastewater

The world's attention is drawn to the widespread ingestion, toxicity, and bioaccumulation of the Atrazine (AT) and Endosulfan (ES). Pesticides have been proven to have endocrine-disrupting, genotoxic, and persistent characteristics. In this work, the structural design of green synthesized NiFe2O4 is incorporated in rice husk biochar to form BC@NiFe2O4 nanocomposite. Powder X-ray diffraction and microscopic analysis confirmed the semi-crystalline nature of BC@NiFe2O4 reduced due to the incorporation of amorphous BC. The green BC@NiFe2O4 nanocomposite degraded AT and ES up to 98 % and 92 %, respectively. The maximum degradation achieved by BC@NiFe2O4 nanocomposite with minimum pollutants concentration (50 mg L−1) with 10 mg catalyst dose at acidic pH in natural sunlight because of the higher negative value of zeta potential (−26.4 mV) and lower band gap (2.5 eV). The degradation process involves first-order kinetics followed by initial Langmuir adsorption. The presence of various radical quenchers (t-BuOH, p-BZQ, Na2EDTA) has led to the conclusion that hydroxyl radicals play a significant role in the degradation of the toxic substances AT and ES. Additionally, a green-fabricated BC@NiFe2O4 nanocomposite has exhibited exceptional efficiency in degrading AT and ES pollutants in actual wastewater samples. Furthermore, this nanocomposite has demonstrated outstanding sustainability and cost-effectiveness, maintaining its effectiveness for up to eight cycles without a noticeable reduction in activity. In summary, due to its favorable surface characteristics, the environmentally friendly BC@NiFe2O4 nanocomposite holds excellent promise as a unique and potential photocatalyst for various industrial applications. [Display omitted] •Facile, cost-effective and green approach for synthesis of BC@NiFe2O4 nanocomposite.•Removal of AT and ES pesticides followed first order kinetics.•BC@NiFe2O4 degraded pesticides AT (98 %), ES (92 %) from agriculture wastewater.•Excellent reusability up to 8th cycles ensures it stability and sustainability.