1,3-Butadiene Production by Simple Dehydrogenation of 1-Butene in the Presence of Steam Over Pt Supported on SnO2-Coated Al2O3
Simple dehydrogenation of 1-butene to form 1,3-butadiene was performed at 550–620 °C using Pt/SnO 2 -Al 2 O 3 catalysts (SnO 2 = 0–23 wt%) in the presence of steam. The low SnO 2 content catalyst (7 wt%) showed high selectivity to 1,3-butadiene, but the catalytic activity dramatically decreased due...
Gespeichert in:
| Veröffentlicht in: | Catalysis letters 2024, Vol.154 (1), p.217-223 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 223 |
|---|---|
| container_issue | 1 |
| container_start_page | 217 |
| container_title | Catalysis letters |
| container_volume | 154 |
| creator | Ishizaki, Takaki Usui, Mitsuki Kuchiki, Seiji Hirahara, Miru Ogihara, Hitoshi Kurokawa, Hideki Miura, Hiroshi |
| description | Simple dehydrogenation of 1-butene to form 1,3-butadiene was performed at 550–620 °C using Pt/SnO
2
-Al
2
O
3
catalysts (SnO
2
= 0–23 wt%) in the presence of steam. The low SnO
2
content catalyst (7 wt%) showed high selectivity to 1,3-butadiene, but the catalytic activity dramatically decreased due to coke formation during the dehydrogenation. With increasing SnO
2
content in the catalyst, the deactivation was suppressed by a decreasing amount of coke. The high one-pass yield (30%) was obtained at 620 °C using the Pt/SnO
2
-Al
2
O
3
catalyst containing 18.0 wt% SnO
2
without serious deactivation of the catalyst.
Graphical Abstract |
| doi_str_mv | 10.1007/s10562-023-04281-7 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_3153547453</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2909332422</sourcerecordid><originalsourceid>FETCH-LOGICAL-c303t-c3715d7d620788b92a4bf04df7c8f34a7ee853465f7571f53368e81fe7d3f9a23</originalsourceid><addsrcrecordid>eNp9kU9rGzEQxUVpoKnTL9CToJccqkTSrKzdo-u2ScDggFPwTci7I3vDWtpIuwVf8tmzawcCOeQyf5j3eww8Qr4LfiU419dJcDWVjEtgPJO5YPoTORdKS5brYv15mLkQDLRcfyFfU3rknBdaFOfkWfwE9qvvbFWjR3ofQ9WXXR083Rzoqt63DdLfuDtUMWzR2-MlOCpGZgRqT7vdyGFCX-J4W3Vo93T5HyO97-iqb9sQO6zoQK78UrJ5sOM6a-QSLsiZs03Cb699Qv79_fMwv2WL5c3dfLZgJXDohqqFqnQ1lVzn-aaQNts4nlVOl7mDzGrEXEE2VU4rLZwCmOaYC4e6AldYCRNyefJtY3jqMXVmX6cSm8Z6DH0yIBSoTGcDOSE_3kkfQx_98J2RBS8AZCZHQ3lSlTGkFNGZNtZ7Gw9GcDNGYk6RmCESc4zE6AGCE5QGsd9ifLP-gHoBlZeMpQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2909332422</pqid></control><display><type>article</type><title>1,3-Butadiene Production by Simple Dehydrogenation of 1-Butene in the Presence of Steam Over Pt Supported on SnO2-Coated Al2O3</title><source>Springer Nature - Complete Springer Journals</source><creator>Ishizaki, Takaki ; Usui, Mitsuki ; Kuchiki, Seiji ; Hirahara, Miru ; Ogihara, Hitoshi ; Kurokawa, Hideki ; Miura, Hiroshi</creator><creatorcontrib>Ishizaki, Takaki ; Usui, Mitsuki ; Kuchiki, Seiji ; Hirahara, Miru ; Ogihara, Hitoshi ; Kurokawa, Hideki ; Miura, Hiroshi</creatorcontrib><description>Simple dehydrogenation of 1-butene to form 1,3-butadiene was performed at 550–620 °C using Pt/SnO
2
-Al
2
O
3
catalysts (SnO
2
= 0–23 wt%) in the presence of steam. The low SnO
2
content catalyst (7 wt%) showed high selectivity to 1,3-butadiene, but the catalytic activity dramatically decreased due to coke formation during the dehydrogenation. With increasing SnO
2
content in the catalyst, the deactivation was suppressed by a decreasing amount of coke. The high one-pass yield (30%) was obtained at 620 °C using the Pt/SnO
2
-Al
2
O
3
catalyst containing 18.0 wt% SnO
2
without serious deactivation of the catalyst.
Graphical Abstract</description><identifier>ISSN: 1011-372X</identifier><identifier>EISSN: 1572-879X</identifier><identifier>DOI: 10.1007/s10562-023-04281-7</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Aluminum oxide ; Butadiene ; Catalysis ; Catalysts ; Catalytic activity ; Chemistry ; Chemistry and Materials Science ; Coke ; Deactivation ; Dehydrogenation ; Electron microscopes ; Gases ; Industrial Chemistry/Chemical Engineering ; Organometallic Chemistry ; Physical Chemistry ; steam ; Tin dioxide</subject><ispartof>Catalysis letters, 2024, Vol.154 (1), p.217-223</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c303t-c3715d7d620788b92a4bf04df7c8f34a7ee853465f7571f53368e81fe7d3f9a23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10562-023-04281-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10562-023-04281-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Ishizaki, Takaki</creatorcontrib><creatorcontrib>Usui, Mitsuki</creatorcontrib><creatorcontrib>Kuchiki, Seiji</creatorcontrib><creatorcontrib>Hirahara, Miru</creatorcontrib><creatorcontrib>Ogihara, Hitoshi</creatorcontrib><creatorcontrib>Kurokawa, Hideki</creatorcontrib><creatorcontrib>Miura, Hiroshi</creatorcontrib><title>1,3-Butadiene Production by Simple Dehydrogenation of 1-Butene in the Presence of Steam Over Pt Supported on SnO2-Coated Al2O3</title><title>Catalysis letters</title><addtitle>Catal Lett</addtitle><description>Simple dehydrogenation of 1-butene to form 1,3-butadiene was performed at 550–620 °C using Pt/SnO
2
-Al
2
O
3
catalysts (SnO
2
= 0–23 wt%) in the presence of steam. The low SnO
2
content catalyst (7 wt%) showed high selectivity to 1,3-butadiene, but the catalytic activity dramatically decreased due to coke formation during the dehydrogenation. With increasing SnO
2
content in the catalyst, the deactivation was suppressed by a decreasing amount of coke. The high one-pass yield (30%) was obtained at 620 °C using the Pt/SnO
2
-Al
2
O
3
catalyst containing 18.0 wt% SnO
2
without serious deactivation of the catalyst.
Graphical Abstract</description><subject>Aluminum oxide</subject><subject>Butadiene</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coke</subject><subject>Deactivation</subject><subject>Dehydrogenation</subject><subject>Electron microscopes</subject><subject>Gases</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Organometallic Chemistry</subject><subject>Physical Chemistry</subject><subject>steam</subject><subject>Tin dioxide</subject><issn>1011-372X</issn><issn>1572-879X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9kU9rGzEQxUVpoKnTL9CToJccqkTSrKzdo-u2ScDggFPwTci7I3vDWtpIuwVf8tmzawcCOeQyf5j3eww8Qr4LfiU419dJcDWVjEtgPJO5YPoTORdKS5brYv15mLkQDLRcfyFfU3rknBdaFOfkWfwE9qvvbFWjR3ofQ9WXXR083Rzoqt63DdLfuDtUMWzR2-MlOCpGZgRqT7vdyGFCX-J4W3Vo93T5HyO97-iqb9sQO6zoQK78UrJ5sOM6a-QSLsiZs03Cb699Qv79_fMwv2WL5c3dfLZgJXDohqqFqnQ1lVzn-aaQNts4nlVOl7mDzGrEXEE2VU4rLZwCmOaYC4e6AldYCRNyefJtY3jqMXVmX6cSm8Z6DH0yIBSoTGcDOSE_3kkfQx_98J2RBS8AZCZHQ3lSlTGkFNGZNtZ7Gw9GcDNGYk6RmCESc4zE6AGCE5QGsd9ifLP-gHoBlZeMpQ</recordid><startdate>2024</startdate><enddate>2024</enddate><creator>Ishizaki, Takaki</creator><creator>Usui, Mitsuki</creator><creator>Kuchiki, Seiji</creator><creator>Hirahara, Miru</creator><creator>Ogihara, Hitoshi</creator><creator>Kurokawa, Hideki</creator><creator>Miura, Hiroshi</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PHGZM</scope><scope>PHGZT</scope><scope>PKEHL</scope><scope>PQEST</scope><scope>PQGLB</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>7S9</scope><scope>L.6</scope></search><sort><creationdate>2024</creationdate><title>1,3-Butadiene Production by Simple Dehydrogenation of 1-Butene in the Presence of Steam Over Pt Supported on SnO2-Coated Al2O3</title><author>Ishizaki, Takaki ; Usui, Mitsuki ; Kuchiki, Seiji ; Hirahara, Miru ; Ogihara, Hitoshi ; Kurokawa, Hideki ; Miura, Hiroshi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c303t-c3715d7d620788b92a4bf04df7c8f34a7ee853465f7571f53368e81fe7d3f9a23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Aluminum oxide</topic><topic>Butadiene</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coke</topic><topic>Deactivation</topic><topic>Dehydrogenation</topic><topic>Electron microscopes</topic><topic>Gases</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Organometallic Chemistry</topic><topic>Physical Chemistry</topic><topic>steam</topic><topic>Tin dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ishizaki, Takaki</creatorcontrib><creatorcontrib>Usui, Mitsuki</creatorcontrib><creatorcontrib>Kuchiki, Seiji</creatorcontrib><creatorcontrib>Hirahara, Miru</creatorcontrib><creatorcontrib>Ogihara, Hitoshi</creatorcontrib><creatorcontrib>Kurokawa, Hideki</creatorcontrib><creatorcontrib>Miura, Hiroshi</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection (ProQuest)</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest Central (New)</collection><collection>ProQuest One Academic (New)</collection><collection>ProQuest One Academic Middle East (New)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Applied & Life Sciences</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ishizaki, Takaki</au><au>Usui, Mitsuki</au><au>Kuchiki, Seiji</au><au>Hirahara, Miru</au><au>Ogihara, Hitoshi</au><au>Kurokawa, Hideki</au><au>Miura, Hiroshi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>1,3-Butadiene Production by Simple Dehydrogenation of 1-Butene in the Presence of Steam Over Pt Supported on SnO2-Coated Al2O3</atitle><jtitle>Catalysis letters</jtitle><stitle>Catal Lett</stitle><date>2024</date><risdate>2024</risdate><volume>154</volume><issue>1</issue><spage>217</spage><epage>223</epage><pages>217-223</pages><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>Simple dehydrogenation of 1-butene to form 1,3-butadiene was performed at 550–620 °C using Pt/SnO
2
-Al
2
O
3
catalysts (SnO
2
= 0–23 wt%) in the presence of steam. The low SnO
2
content catalyst (7 wt%) showed high selectivity to 1,3-butadiene, but the catalytic activity dramatically decreased due to coke formation during the dehydrogenation. With increasing SnO
2
content in the catalyst, the deactivation was suppressed by a decreasing amount of coke. The high one-pass yield (30%) was obtained at 620 °C using the Pt/SnO
2
-Al
2
O
3
catalyst containing 18.0 wt% SnO
2
without serious deactivation of the catalyst.
Graphical Abstract</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10562-023-04281-7</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1011-372X |
| ispartof | Catalysis letters, 2024, Vol.154 (1), p.217-223 |
| issn | 1011-372X 1572-879X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_3153547453 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Aluminum oxide Butadiene Catalysis Catalysts Catalytic activity Chemistry Chemistry and Materials Science Coke Deactivation Dehydrogenation Electron microscopes Gases Industrial Chemistry/Chemical Engineering Organometallic Chemistry Physical Chemistry steam Tin dioxide |
| title | 1,3-Butadiene Production by Simple Dehydrogenation of 1-Butene in the Presence of Steam Over Pt Supported on SnO2-Coated Al2O3 |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-21T22%3A19%3A30IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=1,3-Butadiene%20Production%20by%20Simple%20Dehydrogenation%20of%201-Butene%20in%20the%20Presence%20of%20Steam%20Over%20Pt%20Supported%20on%20SnO2-Coated%20Al2O3&rft.jtitle=Catalysis%20letters&rft.au=Ishizaki,%20Takaki&rft.date=2024&rft.volume=154&rft.issue=1&rft.spage=217&rft.epage=223&rft.pages=217-223&rft.issn=1011-372X&rft.eissn=1572-879X&rft_id=info:doi/10.1007/s10562-023-04281-7&rft_dat=%3Cproquest_cross%3E2909332422%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2909332422&rft_id=info:pmid/&rfr_iscdi=true |