Fabrication of resin cements capable of disintegrating by near-infrared radiation intended for cemented prosthesis removal

The material concept of resin cements capable of disintegrating due to near-infrared (NIR) radiation was verified. The cements were prepared by adding silicon carbide (SiC), which heats upon absorbing NIR rays, and thermally expandable particles (TEPs) to 4-META/MMA-TBB resin cement. The microtensile bond strength (µTBS) and cytocompatibility of the cements were evaluated. The resin cements with 5 mass% SiC and 20-40 mass% TEPs had significantly lower µTBS after NIR radiation than before NIR radiation, and their cytocompatibility was not decreased by SiC and TEPs additions. Furthermore, in vitro thermal damage tests were performed using the resin cement with 5 mass% SiC and 20 mass% TEPs, a typical composition. The results demonstrated conditions that significantly reduced µTBS and minimized thermal damage by NIR radiation. Although these data are only proof of concept, the possibility that dental devices bonded with these cements could be detached by NIR radiation was demonstrated.