Dual-synergistic effect of medium-entropy metal sulfoselenide nanoparticles toward efficient overall seawater splitting

[Display omitted] Developing efficient and durable electrodes for overall water splitting (OWS) in seawater electrolytes is a major challenge. Herein, we synthesized highly active and stable Fe1.2(CoNi)1.8S3Se3 medium-entropy metal sulfoselenide (MESSe) nanoparticles for the electrodes. The Fe1.2(CoNi)1.8S3Se3 MESSe electrode exhibited excellent electrocatalytic performance in alkaline simulated seawater, with a η100 value of 156 mV for the hydrogen evolution reaction and 262 mV for the oxygen evolution reaction. Compared to Fe1.2(CoNi)1.8S6 sulfide and Fe1.2(CoNi)1.8Se6 selenide, the electronic structure of Fe1.2(CoNi)1.8S3Se3 MESSe positively modulates the adsorption/desorption process of *H/*OH intermediate and significantly reduces the free energy of the rate-determining step, thereby accelerating the reaction kinetics of both hydrogen/oxygen evolution reactions. The performance of OWS is significantly enhanced by utilizing the prepared electrode, enabling it to achieve 100 mA cm−2 with only 1.77 V in alkaline simulated seawater. Furthermore, the durability of the electrode is maintained at this high current density in alkaline simulated seawater, alkaline seawater as well as seawater electrolyte. This work will lay the foundation for the development of innovative medium-entropy metal sulfoselenides, promoting their application in a wide range of electrochemical energy systems operating under extreme conditions.