One-step selective synthesis of doubly and triply fused chiral boroloborole derivatives

One-step selective synthesis of doubly and triply fused chiral boroloborole derivatives

Chiral 3a,6a-dihydroborolo[3,2-b]boroles are obtained in one diastereoselective step from the reactions of ortho-(dihaloboryl)arenes with stannole derivatives via a complex rearrangement of 1-borolyl-2-(dihaloboryl)arene intermediates.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2024-11
Hauptverfasser: Bohlen, Josina L., Wieprecht, Nele, Arrowsmith, Merle, Häfner, Alena, Neder, Marco, Braunschweig, Holger
Format: Artikel
Sprache:eng
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Zusammenfassung:Chiral 3a,6a-dihydroborolo[3,2-b]boroles are obtained in one diastereoselective step from the reactions of ortho-(dihaloboryl)arenes with stannole derivatives via a complex rearrangement of 1-borolyl-2-(dihaloboryl)arene intermediates.
ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/D4CC04433A