Amine-functionalized organically modified silica for the effective adsorption of Chlorpyrifos and Triazophos Residues from Orange juice

Excessive application of pesticides to combat pests in orange fruit has resulted in pervasive buildup of their residues leading to severe risks to human health. The study reports the synthesis of amine-functionalized-organically-modified silica (ormosil) to efficiently extract two target pesticides; chlorpyrifos (CPF) and triazophos (TAP) from orange juice. Synthesized ormosil was characterized using different analytical techniques such as scanning electron microscopy (SEM), thermogravimetric analysis (TGA), and fourier transform infrared spectroscopy (FTIR). Adsorption kinetics of ormosil for CPF and TAP followed a pseudo-first-order indicating a physisorption process with excellent removal efficiencies. Detection limits for CPF and TAP were 0.075 and 0.048 μg L−1, respectively. Similarly, limits of quantification were 0.8 and 0.6 μg L−1. Furthermore, there was no significant decrease in the performance of ormosil against CPF and TAP over six successive adsorptive cycles. These findings underscore the potential of investigated ormosil in food analysis. [Display omitted] •Ormosil was developed to adsorb chlorpyriphos and triazophos residues in orange juice.•Response surface methodology was used for optimization of adsorption parameters.•Ormosil's regeneration studies proved its excellent applicability in food analysis.•Statistical results confirmed efficient removal of pesticide residues from orange juice.