Low temperature magnetic properties of layered compounds : NaLnTiO4 (Ln = Sm, Eu, Gd, Tb, Dy, Ho and Er)

A series of orthorhombic NaLnTiO4 (Ln=lanthanides) has been synthesized and characterized. These compounds all crystallize in A-site ordered n=1 Ruddlesden-Popper phase (An+1BnO3n+1) structure. The weak ferromagnetism with large magnetization has been observed for Ln=Tb and Dy, and non-linear field...

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Veröffentlicht in:Journal of alloys and compounds 2008-01, Vol.448 (1-2), p.38-43
Hauptverfasser: OZAWA, T. C, IKOSHI, A, TANIGUCHI, T, MIZUSAKI, S, NAGATA, Y, NORO, Y, SAMATA, H
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Sprache:eng
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Zusammenfassung:A series of orthorhombic NaLnTiO4 (Ln=lanthanides) has been synthesized and characterized. These compounds all crystallize in A-site ordered n=1 Ruddlesden-Popper phase (An+1BnO3n+1) structure. The weak ferromagnetism with large magnetization has been observed for Ln=Tb and Dy, and non-linear field dependence of magnetization without hysteresis has been observed for Ln=Er and Ho. By performing the symmetry operations, two possible canted spin arrangements have been proposed.
ISSN:0925-8388
1873-4669
DOI:10.1016/j.jallcom.2006.10.055