High Volumetric and Gravimetric Acetylene Uptakes in a Cu-MOF with Tailored Cages

NTUniv-80 exhibits record-high volumetric and gravimetric acetylene (C2H2) uptakes of 210 cm3 (STP) g–1 and 227 cm3 (STP) cm–3 at 295 K and 1 atm, respectively. Grand canonical Monte Carlo (GCMC) simulation indicates that those remarkable C2H2 uptakes are attributed to the open Cu2+ sites and tailor...

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Veröffentlicht in:	Inorganic chemistry 2024-11, Vol.63 (45), p.21758-21762
Hauptverfasser:	Qin, Guoping, Guo, Suer, Chen, Meng, He, Xingge, Zhao, Haitian, Jiang, Junyang, Wang, Yu, Wang, Wei, Wang, Shangyu, Wang, Miao, Sun, Tongming, Forrest, Katherine A., Pham, Tony, Zhang, Mingxing
Format:	Artikel
Sprache:	eng
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Zusammenfassung:	NTUniv-80 exhibits record-high volumetric and gravimetric acetylene (C2H2) uptakes of 210 cm3 (STP) g–1 and 227 cm3 (STP) cm–3 at 295 K and 1 atm, respectively. Grand canonical Monte Carlo (GCMC) simulation indicates that those remarkable C2H2 uptakes are attributed to the open Cu2+ sites and tailored cages.
ISSN:	0020-1669 1520-510X 1520-510X
DOI:	10.1021/acs.inorgchem.4c02687