Catalytic behaviors of ruthenium dioxide films deposited on ferroelectrics substrates, by spin coating process

Catalytic ruthenium dioxide films were deposited by spin-coating process on ferroelectric films mainly constituted of SrBi 2Ta 2O 9 (SBT) and Ba 2NaNb 5O 15 (BNN) phases. After thermal treatment under air, these ferroelectric–catalytic systems were characterized by X-ray diffraction and scanning ele...

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Veröffentlicht in:Applied surface science 2007-12, Vol.254 (5), p.1399-1404
Hauptverfasser: Khachane, M., Nowakowski, P., Villain, S., Gavarri, J.R., Muller, Ch, Elaatmani, M., Outzourhite, A., Luk’yanchuk, I., Zegzouti, A., Daoud, M.
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Sprache:eng
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Zusammenfassung:Catalytic ruthenium dioxide films were deposited by spin-coating process on ferroelectric films mainly constituted of SrBi 2Ta 2O 9 (SBT) and Ba 2NaNb 5O 15 (BNN) phases. After thermal treatment under air, these ferroelectric–catalytic systems were characterized by X-ray diffraction and scanning electron microscopy (SEM). SEM images showed that RuO 2 film morphology depended on substrate nature. A study of CH 4 conversion into CO 2 and H 2O was carried out using these catalytic–ferroelectric multilayers: the conversion was analyzed from Fourier transform infrared (FTIR) spectroscopy, at various temperatures. Improved catalytic properties were observed for RuO 2 films deposited on BNN oxide layer.
ISSN:0169-4332
1873-5584
DOI:10.1016/j.apsusc.2007.06.059