Differences in the Reaction Mechanisms of Chlorine Atom and Hydroxyl Radical with Organic Compounds: From Thermodynamics to Kinetics

Hydroxyl radical (HO•) and chlorine atom (Cl•) are common reactive species in aqueous environments. However, the intrinsic difference in their reactions with organic compounds has not been revealed. This study compared the reaction mechanisms of HO• and Cl• with 13 aromatic and 11 aliphatic compound...

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Veröffentlicht in:	Environmental science & technology 2024-10, Vol.58 (40), p.17886-17897
Hauptverfasser:	Qin, Wenlei, Guo, Kaiheng, Chen, Chunyan, Fang, Jingyun
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation energy Aliphatic compounds Aqueous environments Aromatic compounds Cations Chemical compounds Chemical reactions Chlorine Chlorine - chemistry Contaminants Electron transfer Flash photolysis Free energy Hydrogen atoms Hydroxyl Radical - chemistry Hydroxyl radicals Information processing Kinetics Occurrence, Fate, and Transport of Aquatic and Terrestrial Contaminants Organic Chemicals - chemistry Organic compounds Oxidation Oxidation-Reduction Photolysis Quantum chemistry Rate constants Reaction mechanisms Single electrons Solvation Thermodynamics
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