Stereoselective Construction of the ABCDE Pentacyclic Motif of Phainanoids via Norrish–Yang Photocyclization Reaction

Stereoselective Construction of the ABCDE Pentacyclic Motif of Phainanoids via Norrish–Yang Photocyclization Reaction

A Norrish–Yang photocyclization reaction has been applied to regio- and stereoselective construction of the ABCDE pentacyclic motif of natural product phainanoids. The observed substrate conformation control implicates this powerful reaction could be applied to the construction of structurally diver...

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Veröffentlicht in:Organic letters 2024-10, Vol.26 (39), p.8217-8221
Hauptverfasser: Zhou, Yi-Ke, Zhang, Zhen-Yu, Liu, Hao-Yuan, Li, Yuan-He, Zhang, Zhong-Chao, Chen, Jia-Hua, Yang, Zhen
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container_end_page 8221
container_issue 39
container_start_page 8217
container_title Organic letters
container_volume 26
creator Zhou, Yi-Ke
Zhang, Zhen-Yu
Liu, Hao-Yuan
Li, Yuan-He
Zhang, Zhong-Chao
Chen, Jia-Hua
Yang, Zhen
description A Norrish–Yang photocyclization reaction has been applied to regio- and stereoselective construction of the ABCDE pentacyclic motif of natural product phainanoids. The observed substrate conformation control implicates this powerful reaction could be applied to the construction of structurally diverse natural product scaffolds.
doi_str_mv 10.1021/acs.orglett.4c02411
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title Stereoselective Construction of the ABCDE Pentacyclic Motif of Phainanoids via Norrish–Yang Photocyclization Reaction
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