Stereoselective Construction of the ABCDE Pentacyclic Motif of Phainanoids via Norrish–Yang Photocyclization Reaction
A Norrish–Yang photocyclization reaction has been applied to regio- and stereoselective construction of the ABCDE pentacyclic motif of natural product phainanoids. The observed substrate conformation control implicates this powerful reaction could be applied to the construction of structurally diver...
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| Veröffentlicht in: | Organic letters 2024-10, Vol.26 (39), p.8217-8221 |
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| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A Norrish–Yang photocyclization reaction has been applied to regio- and stereoselective construction of the ABCDE pentacyclic motif of natural product phainanoids. The observed substrate conformation control implicates this powerful reaction could be applied to the construction of structurally diverse natural product scaffolds. |
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| ISSN: | 1523-7060 1523-7052 1523-7052 |
| DOI: | 10.1021/acs.orglett.4c02411 |