Controlling and predicting alkyl-onium electronic structure

Controlling and predicting alkyl-onium electronic structure

X-ray photoelectron spectroscopy (XPS) and calculations show that fully alkylated onium cation electronic structure can be tuned using both the alkyl chains and the central onium atom. The key for tuning the central onium atom is methyl longer alkyl chains, allowing selection of the optimum cation f...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2024-09, Vol.60 (77), p.10756-10759
Hauptverfasser: Tompkins, Frances K Towers, Parker, Lewis G, Fogarty, Richard M, Seymour, Jake M, Gousseva, Ekaterina, Grinter, David C, Palgrave, Robert G, Smith, Christopher D, Bennett, Roger A, Matthews, Richard P, Lovelock, Kevin R J
Format: Artikel
Sprache:eng
Schlagworte:
Alkylation
Biocides
Cations
Electronic structure
Photoelectrons
Predictive control
X ray photoelectron spectroscopy
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:X-ray photoelectron spectroscopy (XPS) and calculations show that fully alkylated onium cation electronic structure can be tuned using both the alkyl chains and the central onium atom. The key for tuning the central onium atom is methyl longer alkyl chains, allowing selection of the optimum cation for a wide range of applications, including catalysis and biocides.
ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/d4cc03388d