A direct oxidative esterification of aldehydes with alcohols mediated by photochemical C-H bromination

A direct oxidative esterification of aldehydes with alcohols mediated by photochemical C-H bromination

The photochemical direct esterification of aldehydes with alcohols -generated acyl-bromides presented in this report is an attractive complementary addition to hitherto reported methods, as these are usually carried out in a two-step, one-pot procedure in order to avoid side reactions such as the ox...

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Veröffentlicht in:Organic & biomolecular chemistry 2024-11, Vol.22 (46), p.9032-9035
Hauptverfasser: Ando, Haru, Kodaki, Sakura, Takamura, Hiroyoshi, Kadota, Isao, Tanaka, Kenta
Format: Artikel
Sprache:eng
Schlagworte:
Alcohols
Aldehydes
Bromides
Bromination
Esterification
Oxidation
Photochemicals
Side reactions
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Zusammenfassung:The photochemical direct esterification of aldehydes with alcohols -generated acyl-bromides presented in this report is an attractive complementary addition to hitherto reported methods, as these are usually carried out in a two-step, one-pot procedure in order to avoid side reactions such as the oxidation of alcohols by halogen sources.
ISSN:1477-0520
1477-0539
1477-0539
DOI:10.1039/d4ob01237b