Hybrid materials comprising ferrocene and diaminoborane moieties: linear concatenation versus macrocyclization

Combination of borane and diaminoferrocene monomers by Si/B exchange condensation reactions afforded either diazabora-[3]ferrocenophanes or, stepwise processes, larger macrocycles and a series of linear oligomers. Additional incorporation of -phenylene moieties in the backbone yielded alternating co...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2024-10, Vol.60 (82), p.11706-11709
Hauptverfasser: Schneider, Johannes S, Helten, Holger
Format: Artikel
Sprache:eng
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Zusammenfassung:Combination of borane and diaminoferrocene monomers by Si/B exchange condensation reactions afforded either diazabora-[3]ferrocenophanes or, stepwise processes, larger macrocycles and a series of linear oligomers. Additional incorporation of -phenylene moieties in the backbone yielded alternating concatenation.
ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/d4cc03813d