catena-Pol[[bis(nitrato-Kappa2O,O')- copper(II)]-mu-propane-1,3-diylbis(diphenylphosphine oxide)-Kappa2O:O']

catena-Pol[[bis(nitrato-Kappa2O,O')- copper(II)]-mu-propane-1,3-diylbis(diphenylphosphine oxide)-Kappa2O:O']

The structure of the title complex, [Cu(NO3)2(C27H26O2P2)]n, consists of polymeric chains formed by propane-1,3-diyl-bis(diphenylphosphine oxide) ligands bridging between metal centres. The Cu atom lies on a twofold rotation axis and a further symmetry centre bisects the bridging bisphosphine dioxid...

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Veröffentlicht in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2007-10, Vol.63 (10), p.m433-m435
Hauptverfasser: Platt, Andrew W G, Lees, Anthony M J
Format: Artikel
Sprache:eng
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Zusammenfassung:The structure of the title complex, [Cu(NO3)2(C27H26O2P2)]n, consists of polymeric chains formed by propane-1,3-diyl-bis(diphenylphosphine oxide) ligands bridging between metal centres. The Cu atom lies on a twofold rotation axis and a further symmetry centre bisects the bridging bisphosphine dioxide ligand. The CuO6 coordination geometry is a distorted octahedron, with the bidentate chelating nitrate groups adopting a cis configuration.
ISSN:0108-2701
DOI:10.1107/S0108270107038711