The electrophilic methylating agent SO2Me+ parent of two cationic species
Methylfluoride and hydrogen fluoride react with powerful methylating agent [SO2Me]+ in a temperature-dependent addition reaction to form methylated fluorosulfuric acid [FS(OMe)2][Sb2F11] and methylated fluorosulfuric acid methyl ester [FS(OH)(OMe)][SbF6], respectively. The obtained methylated fluoro...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2024-09, Vol.60 (74), p.10148 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Methylfluoride and hydrogen fluoride react with powerful methylating agent [SO2Me]+ in a temperature-dependent addition reaction to form methylated fluorosulfuric acid [FS(OMe)2][Sb2F11] and methylated fluorosulfuric acid methyl ester [FS(OH)(OMe)][SbF6], respectively. The obtained methylated fluorosulfinic acid and methylated fluorosulfinic acid methyl ester were characterized by single X-ray structure analysis and vibrational spectroscopy.Methylfluoride and hydrogen fluoride react with powerful methylating agent [SO2Me]+ in a temperature-dependent addition reaction to form methylated fluorosulfuric acid [FS(OMe)2][Sb2F11] and methylated fluorosulfuric acid methyl ester [FS(OH)(OMe)][SbF6], respectively. The obtained methylated fluorosulfinic acid and methylated fluorosulfinic acid methyl ester were characterized by single X-ray structure analysis and vibrational spectroscopy. |
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| ISSN: | 1364-548X 1364-548X |
| DOI: | 10.1039/d4cc03400g |