Analysis of Lithium Aging Using Machine Learning-Enhanced Spectroscopy Techniques

Lithium compounds such as lithium hydride (LiH) and lithium hydroxide (LiOH) have a wide range of industrial applications, but are highly reactive in environments with H2O and CO2. These reactions lead to the ingrowth of secondary lithium compounds, which can alter the homogeneity and affect the app...

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Veröffentlicht in:Applied spectroscopy 2024-08, Vol.78 (8), p.874-884
Hauptverfasser: Stofel, James T., Rao, Ashwin P., Patnaik, Anil K., Giminaro, Andrew V., Shattan, Michael B.
Format: Artikel
Sprache:eng
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Zusammenfassung:Lithium compounds such as lithium hydride (LiH) and lithium hydroxide (LiOH) have a wide range of industrial applications, but are highly reactive in environments with H2O and CO2. These reactions lead to the ingrowth of secondary lithium compounds, which can alter the homogeneity and affect the application of particular lithium chemicals. This study performed an exploratory analysis of different lithium compounds using laser-induced breakdown spectroscopy (LIBS) and Raman spectroscopy. Machine learning models are trained on the recorded spectral data to discriminate emission features that differ between LiH, LiOH, and Li2CO3 to perform high-fidelity classification. Support vector machine classifiers yield perfect prediction accuracy between the three compounds with optimal training time. Multivariate methods are then used to produce regression models quantifying the ingrowth of LiOH in LiH. Performing a mid-level data fusion of selected LIBS and Raman features with partial least-squares regression produces the superlative model with a root mean square error of 2.5 wt % and a detection limit of 6.3 wt % .
ISSN:0003-7028
1943-3530
1943-3530
DOI:10.1177/00037028241235679