Liquidlike, Low‐Friction Polymer Brushes for Microfibre Release Prevention from Textiles

During synthetic textile washing, rubbing between fibres or against the washing machine, exacerbated by the elevated temperature, initiates the release of millions of microplastic fibres into the environment. A general tribological strategy is reported that practically eliminates the release of microplastic fibres from laundered apparel. The two‐layer fabric finishes combine low‐friction, liquidlike polymer brushes with “molecular primers”, that is, molecules that durably bond the low‐friction layers to the surface of the polyester or nylon fabrics. It is shown that when the coefficient of friction is below a threshold of 0.25, microplastic fibre release is substantially reduced, by up to 96%. The fabric finishes can be water‐wicking or water‐repellent, and their comfort properties are retained after coating, indicating a tunable and practical strategy toward a sustainable textile industry and plastic‐free oceans and marine foodstuffs. Liquidlike, low‐friction polymer brush fabric finishes are successfully developed using molecular primers based on sulfonate‐ or amino‐functionalized silanes. These primers strongly bond the polymer brushes with fabrics to enhance wash durability. Owing to the low coefficient of friction, the finished fabrics release a significantly reduced number of microplastic fibres (MPFs) and show good breathability, wettability, and comfort properties.