Polyμ3-2-(benzotriazol-1-yl)acetato-κ3 O:O':N 3chlorido-(ethanol-κO)cobalt(II)

In the title compound, [Co(C8H6N3O2)Cl(C2H5OH)] n , the CoII atoms adopt octa-hedral trans-CoN2O4 and tetra-hedral CoCl2O2 coordination geometries (site symmetries and m, respectively). The bridging μ3-O:O:N 2-(benzotriazol-1-yl)acetato ligands connect the octa-hedral cobalt nodes into (010) sheets...

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Veröffentlicht in:IUCrData 2024-07, Vol.9 (Pt 7), p.x240630
Hauptverfasser: Zheng, Yun-Yun, Su, De-Sen, Yao, Qing-Hua, Huang, Min-Min
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title compound, [Co(C8H6N3O2)Cl(C2H5OH)] n , the CoII atoms adopt octa-hedral trans-CoN2O4 and tetra-hedral CoCl2O2 coordination geometries (site symmetries and m, respectively). The bridging μ3-O:O:N 2-(benzotriazol-1-yl)acetato ligands connect the octa-hedral cobalt nodes into (010) sheets and the CoCl2 fragments link the sheets into a tri-periodic network. The structure displays O-H⋯O hydrogen bonding and the ethanol mol-ecule is disordered over two orientations.In the title compound, [Co(C8H6N3O2)Cl(C2H5OH)] n , the CoII atoms adopt octa-hedral trans-CoN2O4 and tetra-hedral CoCl2O2 coordination geometries (site symmetries and m, respectively). The bridging μ3-O:O:N 2-(benzotriazol-1-yl)acetato ligands connect the octa-hedral cobalt nodes into (010) sheets and the CoCl2 fragments link the sheets into a tri-periodic network. The structure displays O-H⋯O hydrogen bonding and the ethanol mol-ecule is disordered over two orientations.
ISSN:2414-3146
2414-3146
DOI:10.1107/S2414314624006308