Employing transfer-dominated branching radical telomerisation (TBRT) and atom transfer radical polymerisation (ATRP) to form complex polyester-polymethacrylate branched-linear star copolymer hybrids via orthogonal initiation

Employing transfer-dominated branching radical telomerisation (TBRT) and atom transfer radical polymerisation (ATRP) to form complex polyester-polymethacrylate branched-linear star copolymer hybrids via orthogonal initiation

TBRT and ATRP are orthogonal initiation chemistries used in vinyl polymerisations. Here, we present the first combination of these techniques to readily create high molecular weight branched polyester macroinitiators capable of forming star copolymers from a range of methacrylate monomers.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2024-09, Vol.60 (74), p.10116-10119
Hauptverfasser: Dwyer, Andrew B, Sandy, William, Hern, Faye Y, Penrhyn-Lowe, Oliver B, McKeating, Samuel, Flynn, Sean, Wright, Stephen, Pate, Sophie, Chambon, Pierre, Rannard, Steve P
Format: Artikel
Sprache:eng
Schlagworte:
Copolymers
Initiation (polymerization)
Polymerization
Polymethacrylates
Star formation
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Beschreibung
Zusammenfassung:TBRT and ATRP are orthogonal initiation chemistries used in vinyl polymerisations. Here, we present the first combination of these techniques to readily create high molecular weight branched polyester macroinitiators capable of forming star copolymers from a range of methacrylate monomers.
ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/d4cc02142h