Hectogram‐Scale Synthesis of Visible Light Excitable Room Temperature Phosphorescence Carbon Dots

Carbon dots (CDs) based room temperature phosphorescence (RTP) materials can be prepared via facile procedures and exhibit excellent photostability and biocompatibility. Furthermore, doping of hetero‐atoms into CDs can afford multiple triplet levels. The RTP emission generated from the resultant CDs always displays outstanding dynamic behaviors and even can be efficiently excited by visible light. Given this, CDs‐based RTP materials not only can be used for anti‐counterfeiting but also exhibit great application potential in signage and illumination fields. In this contribution, a type of B, N, and P co‐doped CDs are prepared in hectogram scale. Upon excitation by UV lamp and white LED, the obtained CDs emit green and yellow RTP, respectively, the lifetime of which are 851 and 481 ms, respectively. It is found that the luminescence color of the CDs can be further tuned. By controlling the degree of carbonization, the RTP color of the CDs can be facilely tuned from green to orange‐red. Based on an energy transfer strategy, the luminescence color can be further tuned to red. Benefited from the dynamic and visible‐excited colorful RTP emission, the application of these obtained CDs in anti‐counterfeiting, fingerprint collection, and luminescent traffic signage are also explored. A type of B, N, and P co‐doped carbon dots (BNP‐CDs) are prepared in hectogram‐scale. The obtained BNP‐CDs display multiple colored and excitation‐dependent room temperature phosphorescence emissions. Especially, upon irradiation by visible light, they also emit yellow to orange‐red RTP. The application of them in anti‐counterfeiting, fingerprint collection, and luminescent traffic signage is explored as well.