Trapping an Elusive Fe(IV)-Superoxo Intermediate Inside a Self-Assembled Nanocage in Water at Room Temperature

Molecular cavities that mimic natural metalloenzymes have shown the potential to trap elusive reaction intermediates. Here, we demonstrate the formation of a rare yet stable Fe­(IV)-superoxo intermediate at room temperature subsequent to dioxygen binding at the Fe­(III) site of a (Et4N)2[FeIII(Cl)­(...

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Veröffentlicht in:Journal of the American Chemical Society 2024-08, Vol.146 (31), p.21729-21741
Hauptverfasser: Gera, Rahul, De, Puja, Singh, Kundan K., Jannuzzi, Sergio A. V., Mohanty, Aisworika, Velasco, Lucia, Kulbir, Kumar, Pankaj, Marco, J. F., Nagarajan, Kalaivanan, Pecharromán, Carlos, Rodríguez-Pascual, P. M., DeBeer, Serena, Moonshiram, Dooshaye, Gupta, Sayam Sen, Dasgupta, Jyotishman
Format: Artikel
Sprache:eng
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