In Situ Pyrolysis of ZIF-67 to Construct Co2N0.67@ZIF-67 for Photocatalytic CO2 Cycloaddition Reaction

The development of heterogeneous catalysts with abundant active sites is pivotal for enhancing the efficiency of photothermal CO2 conversion. Herein, we report the construction of Co2N0.67@ZIF-67 through the in situ pyrolysis of ZIF-67 under low-temperature pyrolysis conditions. During the pyrolysis process, the crystal structure of ZIF-67 is predominantly preserved concurrently with the formation of Co2N0.67 nanoparticles (NPs) within the ZIF-67 pores. The optimal catalyst Co2N0.67@ZIF-67­(450,2) not only possesses high photothermal efficiency but also can efficiently activate CO2. Benefiting from these characteristics, Co2N0.67@ZIF-67­(450,2) exhibited significant catalytic activity in the photocatalytic cycloaddition of CO2 and epichlorohydrin. The yield of (chloromethyl)­ethylene carbonate reached 95%, which is more than 4 times higher than that of ZIF-67 under visible light irradiation (300 W·m2 Xe lamp, 3 h). This study could offer an alternative approach to enhance the photocatalytic activity of MOFs through low-temperature pyrolysis.