Cesium stability on the interlayers of K- or Rb-fixing micaceous minerals investigated by both experimental and numerical simulation methods

The frayed edge site (FES) of micas, a partially weathered interlayer site, selectively adsorbs Cs radioisotopes. Despite extensive research on Cs+ adsorption, the interactive dynamics of FES elements remain unclear. This study employs experimental and computational methods to examine how interlayer cations at the FES affect Cs stability. We measured the solid–liquid distribution coefficients of Cs+ for partially expanded K- and Rb-fixed biotite using chemical extraction and adsorption methods. We evaluated the standard Gibbs free energy for the Cs exchange reaction between the FESs of K- and Rb-fixed muscovite models and bulk water, expanding the d001 spacing from collapsed to fully expanded conditions. Our results reveal that the interlayer cation significantly influences Cs+ affinity for FES, with the substitution of K+ with Rb+ largely reducing Cs+ stability. The computational approach further disclosed that the K+ to Rb+ replacement only at the wedge-shaped part of the FES contributed to the decrease in Cs+ stability whereas the replacement at other interlayer sites caused little impact. Our studies offer microscopic structural insights into FES, highlighting the critical role of the wedge-shaped part of FES in Cs+ stability. [Display omitted] •K+ substitution with Rb+ at a collapsed side of weathered micaceous minerals caused a reduction of cesium stability in interlayer sites.•This was confirmed by both experimental and numerical simulation methods.•The simulation further disclosed that reduced stability of Cs+ results exclusively from the K+ - Rb+ substitution in the wedge-shaped part of interlayer sites.•Thus, we obtained a microscopic structural insights highlighting the critical role of the wedge-shaped part K+ for Cs+ stability.