Joint Exfoliation of MXene by Dimensional Mismatched SiC/ZIF‐67 Toward Multifunctional Flame Retardant Thermoplastic Polyurethane

The single‐layer MXene fully demonstrates the advantages of 2D materials, especially catalytic, conductive, and mechanical properties. However, the high energy consumption and low efficiency faced by MXene in the divestiture process are still challenges that need to be solved urgently. In this article, dimension mismatch and collaborative stripping strategies are skillfully combined to easily realize the transformation from multi‐layer MXene to single layer. In addition, the functionalized MXene@SiC@polyaniline (MXene@SiC@PANI) nano‐hybrid materials are used as fillers to improve the thermal conductivity, flame retardant, and antibacterial properties of thermoplastic polyurethane (TPU). The surface temperature of TPU/MXene@SiC@PANI composites increased from 33.4 °C to 59.8 °C within 10 s. In addition, the antibacterial efficiency of TPU composites against Escherichia coli and Staphylococcus aureus is 69.6% and 88.9%, respectively. Compared with pure TPU, the peak heat release rate and total heat release are reduced by 71.4% and 34.6%, respectively. The flame‐retardant mechanism of MXene hybrid materials is systematically discussed. It is worth noting that the introduction of PANI enhances the compatibility between the filler and the polymer, effectively maintaining the mechanical properties of the TPU itself. This work provides a convenient method for the multi‐functional practical application of TPU. A monolayer of MXene@SiC@ZIF material is prepared by the concept of dimensional mismatch and joint exfoliation. And according to the previous work, polyaniline (PANI) is generated by in situ polymerization on the surface of ZIF‐67 to obtain MXene@SiC@PANI nano‐hybrid material. The thermally conductive, flame retardant, and antibacterial properties of thermoplastic polyurethane are effectively improved.