Preparation of WO3‐Mica Hybrid Coatings with Electrochromic Properties and Pearl Luster

Tungsten oxide‐mica composites were prepared by adding different amounts of commercial mica (alumina silicate) in order to provide high luster to electrochromic coatings. The mechanical stability was sustained for up to 50 weight % mica for application in aqueous medium. The electrochemical properties, coloration, and luster were investigated. The luster of the composites increased roughly linearly with increased mica content and was retained after coloration. The addition of 10 weight % mica was found to be optimal with respect to the compromise between electrochromic coloration and pearlescent luster. This is, to the best of our knowledge, the first report on the preparation and characterization of WO3‐mica inorganic composites with high luster in both bleached and colored states. WO3 composites containing mica (alumina silicate), coated with a thin layer of titania, provides electrochromic coatings with pearlescent appearance and high luster in both the colored and bleached states.