Tuning Octahedron Sites of CoV2O4 via Cationic Competition for Efficient Oxygen Evolution Reaction

Doping transition metal oxide spinels with metal ions represents a significant strategy for optimizing the electronic structure of electrocatalysts. Herein, a bimetallic Fe and Ru doping strategy to fine‐tune the crystal structure of CoV2O4 spinel for highly enhanced oxygen evolution reaction (OER) is presented performance. The incorporation of Fe and Ru is observed at octahedral sites within the CoV2O4 structure, effectively modulating the electronic configuration of Co. Density functional theory calculations have confirmed that Fe acts as a novel reactive site, replacing V. Additionally, the synergistic effect of Fe, Co, and Ru effectively optimizes the Gibbs free energy of the intermediate species, reduces the reaction energy barrier, and accelerates the kinetics toward OER. As expected, the best‐performing CoVFe0.5Ru0.5O4 displays a low overpotential of 240 mV (@10 mA cm−2) and a remarkably low Tafel slope of 38.9 mV dec−1, surpassing that of commercial RuO2. Moreover, it demonstrates outstanding long‐term durability lasting for 72 h. This study provides valuable insights for the design of highly active polymetallic spinel electrocatalysts for energy conversion applications. The well‐designed CoVFe0.5Ru0.5O4 exhibits exceptional oxygen evolution reaction (OER) activity and stability, which can be attributed to the incorporation of Fe and Ru cations replacing the octahedral sites of CoV2O4. This substitution effectively reduces the reaction energy barrier, weakens the oxygen desorption energy, enhances the electrical conductivity, and provides abundant active sites.