Coordination Structure Modulation in Group‐VIB Metal Doped Ag3PO4 Augments Active Site Density for Electrocatalytic Conversion of N2 to NH3

Doping is considered a promising material engineering strategy in electrochemical nitrogen reduction reaction (NRR), provided the role of the active site is rightly identified. This work concerns the doping of group VIB metal in Ag3PO4 to enhance the active site density, accompanied by d‐p orbital mixing at the active site/N2 interface. Doping induces compressive strain in the Ag3PO4 lattice and inherently accompanies vacancy generation, the latter is quantified with positron annihilation lifetime studies (PALS). This eventually alters the metal d‐electronic states relative to Fermi level and manipulate the active sites for NRR resulting into side‐on N2 adsorption at the interface. The charge density deployment reveals Mo as the most efficient dopant, attaining a minimum NRR overpotential, as confirmed by the detailed kinetic study with the rotating ring disk electrode (RRDE) technique. In fact, the Pt ring of RRDE fails to detect N2H4, which is formed as a stable intermediate on the electrode surface, as identified from in‐situ attenuated total reflectance‐infrared (ATR‐IR) spectroscopy. This advocates the complete conversion of N2 to NH3 on Mo/Ag3PO4‐10 and the so‐formed oxygen vacancies formed during doping act as proton scavengers suppressing hydrogen evolution reaction resulting into a Faradaic efficiency of 54.8% for NRR. Group‐VIB metal (Cr, Mo, W) doping in Ag3PO4 brings about significant changes in the lattice d‐spacing (compressive strain) and electronic structure (upshift of d‐band center toward Fermi level) of the catalysts. This doping‐assisted‐vacancy engineering significantly influences N2 adsorption and the first protonation steps of NRR by a d‐p orbital mixing at the active center‐N2 interface, depicting Mo as the strongest contender.