Covalent Organic Framework Nanoarchitectonics: Recent Advances for Precious Metal Recovery

The recovery of precious metals (PMs) from secondary resources has garnered significant attention due to environmental and economic considerations. Covalent organic frameworks (COFs) have emerged as promising adsorbents for this purpose, owing to their tunable pore size, facile functionalization, exceptional chemical stability, and large specific surface area. This review provides an overview of the latest research progress in utilizing COFs to recover PMs. Firstly, the design and synthesis strategies of chemically stable COF‐based materials, including pristine COFs, functionalized COFs, and COF‐based composites, are delineated. Furthermore, the application of COFs in the recovery of gold, silver, and platinum group elements is delved into, emphasizing their high adsorption capacity and selectivity as well as recycling ability. Additionally, various interaction mechanisms between COFs and PM ions are analyzed. Finally, the current challenges faced by COFs in the field of PM recovery are discussed, and potential directions for future development are proposed, including enhancing the recyclability and reusability of COF materials and realizing the high recovery of PMs from actual acidic wastewater. With the targeted development of COF‐based materials, the recovery of PMs can be realized more economically and efficiently in the future. This review explores the advancements in covalent organic frameworks (COFs) for precious metal (PM) recovery, organizing design and synthesis strategies for three types of COF‐based materials. It highlights the selectivity of COFs due to strong interactions with PMs. Importantly, it notes limited research on platinum group elements and real wastewater applications, suggesting future research directions.