Disparate reactivity of a chiral iron() tetracarbene complex with organic azides
A chiral tetra-NHC iron( ii ) complex and its disparate reactivity with multiple organic azides is reported. Both aryl and alkyl azides react with the iron( ii ) complex yielding three distinct products: an iron( iv ) imide, an iron( iv ) tetrazene, and a surprising and unprecedented double imide in...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2024-07, Vol.53 (26), p.1819-1823 |
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| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A chiral tetra-NHC iron(
ii
) complex and its disparate reactivity with multiple organic azides is reported. Both aryl and alkyl azides react with the iron(
ii
) complex yielding three distinct products: an iron(
iv
) imide, an iron(
iv
) tetrazene, and a surprising and unprecedented double imide insertion complex.
A chiral tetra-NHC iron(
ii
) complex and its disparate reactivity with multiple organic azides is reported. |
|---|---|
| ISSN: | 1477-9226 1477-9234 1477-9234 |
| DOI: | 10.1039/d4dt01422g |