A Fluorescent Hydrogel with AIE Emission for Dehydration‐Visualizable Wearable Sensors

Hydrogel‐based wearable sensors eventually experience dehydration, which negatively impacts their function, leading to decreased sensitivity. Monitoring the real‐time water retention rate and sensing performance of wearable flexible sensors without dismantling them remains a significant difficulty. In this study, a molecule having aggregation‐induced emission (AIE) properties in an aqueous environment has been developed and produced, which can combine with anionic guar gum and acrylic acid to create an AIE hydrogel. Wearable sensing electronic devices have the capability to track motion signals at various joints of the human body. Additionally, they can effectively and visually monitor dehydration status during extended periods of operation. The fluorescence intensity of the hydrogel is primarily influenced by the level of aggregation of luminous monomers inside the network. This level of aggregation is predominantly governed by the hydrogel's water retention rate. Hence, the extended duration of hydrogel dehydration can be manifested through alterations in their fluorescence characteristics, which are employed for strain sensing. This approach enables users to assess the water retention of hydrogels with greater efficiency, eliminating the requirement for disassembling them from the completed electrical gadget. In summary, the use of AIE‐based fluorescent hydrogels will advance the progress of intelligent wearable electronics. Herein, a novel AIEgen‐based fluorescent hydrogel as wearable sensing electronic devices, having the capability to simultaneously track motion signals and hydrogel's water retention rate that depends on fluorescence intensity at various joints of the human body, is successfully prepared by the one‐pot strategy.